Research

Scintific Payoffs

ABOUT LIQUID GATING TECHNOLOGY

By learning from nature, the development of liquid gating technology introduces liquids as structural and functional materials with porous solid materials, leveraging the unique properties of liquids to overcome the limitations of traditional solid porous material. Through the synergistic design of porous solid frameworks and gating liquids, liquid gating systems with special properties can be constructed to achieve responsive fluid switching functions under external stimuli. In 2020, "liquid gating technology" was selected as one of the top ten emerging technologies globally by the world-renowned organization IUPAC. The official statement noted that "liquid gating technology enhances the universality of traditional membrane systems, which has milestone significance for the development of multiple interdisciplinary fields such as membrane science and technology, and microfluidics" (from the Chinese Chemical Society's announcement on October 23, 2020). In 2023, "liquid gating technology" was included in undergraduate foundational textbooks.
Advantages
Anti-fouling
Corrosion-resistant
Adaptivity
Energy-efficient
Reconfiguration
Molecular-level smooth interface
Applications
Ecological Environment
Biomedicine
Drug Screening
 Substance Detection
 Carbon Neutrality
 Aerospace and Related Fields

DESIGN OF LIQUID GATING SYSTEM

        A liquid gating mechanism and technology using liquid as a structural material combines a porous solid framework with gating liquid through capillary action. The design of the porous solid framework focuses on the interfacial interaction between the solid material constituting the porous framework and the gating liquid. The solid material must meet three criteria: ① it can be wetted by the gating liquid; ② its wettability with the gating liquid is superior to that with the transported fluid, ensuring that the gating liquid is not displaced by the transported fluid during transmission; ③ its interfacial energy with the gating liquid must be matched so that after the pressure of the transported fluid is released, the gating liquid can reconfigure within the pores to return to the original closed state. The design of the gating liquid focuses on the interaction between the gating liquid and the transported fluid. The immiscibility between the transported fluid and the gating liquid is the fundamental prerequisite for selecting the gating liquid: when the transported fluid is a gas, a water-based or oil-based liquid that is non-volatile and non-reactive with the transported gas can be chosen as the gating liquid; if the transported fluid is a liquid, such as an aqueous solution, an oil-based liquid immiscible with it should be selected as the gating liquid. Commonly used gating liquids include mineral oil, silicone oil, and perfluorinated liquids.

The gating behavior of liquid gating technology

        The core difference between liquid gating technology and traditional membrane technology is that the transported fluid only contacts the gating liquid as it passes through the pores, without contacting the solid membrane material itself. In liquid gating technology, traditional scientific issues that occur at the solid/gas or solid/liquid interfaces are transformed into issues between solid/liquid/gas or solid/liquid/liquid interfaces. The introduction of liquid endows liquid gating membranes with excellent anti-fouling properties, energy efficiency, and design flexibility to meet different functional requirements. Additionally, since different types of transported fluids require different pressures to break through the gas/liquid or liquid/liquid interface, each fluid has a specific transmembrane pressure threshold. This endows liquid gating composite membranes with the ability to selectively separate different types of fluids.

        (a) The liquid stably existing in micron/nano-scale pores can serve as a reversible, reconfigurable pressure-driven gating liquid. When the transported fluid passes through the system, an interface is formed between the transported fluid and the gating liquid; (b)(c) Under certain pressure, the transported fluid deforms the gas/liquid or liquid/liquid interface and passes through the liquid gating composite membrane. The minimum pressure required for this process is the transmembrane pressure threshold (P_threshold). When the pressure of the transported fluid (ΔP) is less than P_threshold, the liquid fills the closed pores under capillary action; conversely, the liquid gate opens, allowing the transported fluid to flow through the pores, forming a functional liquid lining with a stable gas/liquid or liquid/liquid interface within the pores.

The Development Status of Liquid Gate Control Technology

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